Create a config file (<any_name>.config) in /var/lib/connman, with the followinf content:

[service_<any_name>]
Type = wifi
Name = <SSID>
EAP = peap
Phase2 = MSCHAPV2
Identity = <user_name>
Passphrase = <user_password>

where

• <any_name> is a unique identifier among the services in the config file,
• <SSID> is the SSID of the network you want to connect to,
• <user_name> and <user_password> are the credentials for the user to access the network.